Physical And Chemical Properties

Thu, 14 Jun 2012 | Carbon Tetrachloride

See Table 11.2.

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Table 11.1 Some glycol ethers and their acetates (ECETOC, 1995)
Name	Synonyms	CAS	RTECS	UN	EINECS
ethylene glycol (mono) methyl ether	EGME, 2-methoxyethanol, methyl cellosolve	109-86-4	KL 5775000	1188	203-713-7
ethylene glycol (mono) methyl ether acetate	EGMEA, 2-methoxyethyl acetate, methyl cellosolve acetate	110-49-6	KL 5950000	1189	203-772-9
methoxyacetic acid	MAA	625-45-6	Al 8650000	-	210-894-6
ethylene glycol (mono) ethyl ether	EGEE, 2-ethoxyethanol	110-80-5	KK 8050000	1171	203-804-1
ethylene glycol (mono) ethyl ether acetate	EGEEA, 2-ethoxyethyl acetate	111-15-9	KK 8225000	1172	203-839-2
ethylene glycol (mono) «-propyl ether	EGnPE, «-propylethanol	2807-30-9	KM 2800000	-	220-548-6
ethylene glycol (mono) «-propyl ether acetate	EGnPEA, 2-propoxyethyl acetate	20706-25-6	AJ 3345000	-	-
ethylene glycol (mono) iso-propyl ether	EGiPE, 2-isopropoxyethanol	109-59-1	KL 5075000	-	203-685-6
ethylene glycol (mono) «-butyl ether	EGBE, butyl cellusolve, 2-butoxyethanol, butyl glycol	111-76-2	KJ 8575000	2369	203-905-0
ethylene glycol «-butyl ether acetate	EGBEA, 2-«-butoxyethyl acetate	112-07-2	KJ 8925000	-	203-933-3
ethylene glycol (mono) phenyl ether	EGPhE, 2-phenoxyethanol	122-99-6	KM 0350000	-	204-589-7
ethylene glycol dimethyl ether	EGDME, 1,2-dimethoxy ethane	110-71-4	KI1451000	2252	203-794-9
ethylene glycol diethyl ether	EGDEE, 1,2-diethoxy ethanol	629-14-1	KI1225000	1153	211-076-1
diethylene glycol (mono) methyl ether	DEGME, 2-(2-methoxyethoxy)ethanol	111-77-3	KL 6125000	-	203-906-6
diethylene glycol (mono) ethyl ether	DEGEE, 2-(2-ethoxyethoxy)ethanol	111-90-0	KK 8750000	-	203-919-7
diethylene glycol (mono) ethyl ether acetate	DEGEEA, 2-(2-ethoxyethoxy)ethanol acetate	112-15-2	KK 8925000	-	203-940-1
diethylene glycol (mono) butyl ether	DEGBE, 2-(2-«-butoxyethoxy)ethanol	112-34-5	KJ 9100000	-	203-961-6
diethylene glycol butyl ether acetate	DEGBEA, 2-(2-butoxyethoxy)ethyl acetate	124-17-4	KJ 9275000	-	204-685-9
diethylene glycol dimethyl ether	DEGDME, bis (2-methoxyethyl)ether	111-96-6	KN 3339000	-	203-924-4
diethylene glycol diethyl ether	DEGDEE, bis (2-ethoxyethyl)ether	112-36-7	KN 3160000	-	203-963-7
triethylene glycol (mono) methyl ether	TEGME, 2-[2-(methoxyethoxy)ethoxy]ethanol	112-35-6	KL 6390000	-	203-962-1
triethylene glycol (mono) ethyl ether	TEGEE, 2-[2-(2-ethoxyethoxy)ethoxy)ethanol	112-50-5	KK 8950000	-	203-978-9
triethylene glycol (mono) «-butyl ether	TEGBE, 2-[2-(2-butoxyethoxy)ethoxy]ethanol	143-22-6	KJ 9450000	-	205-592-6

Table 11.1 Some glycol ethers and their acetates (ECETOC, 1995) continued
Name	Synonyms	CAS	RTECS	UN	EINECS
triethylene glycol dimethyl ether	TEGDME, 2,5,8,11-tetraoxadodecane	112-49-2	XF 0665000	-	203-977-3
2-propylene glycol 1-methyl ether	2PG1ME, l-methoxy-2-propanol	107-98-2	UB 7700000	3092	203-539-1
2-propylene glycol 1-methyl ether 2-acetate	2PG1MEA, 1 -methoxy-2-acetoxypropane	108-65-6	AI 8925000	-	203-603-9
2-propylene glycol 1-ethyl ether	2PG1EE, l-ethoxy-2-propanol	1569-02-4	UB 5250000	-	216-374-5
2-propylene glycol 1-ethyl ether 2-acetate	2PG1 EEA, 1 -ethoxy-2-acetoxypropanol	54839-24-6	-	-	259-370-9
2-propylene glycol 1-«-butyl ether	2PG1BE, l-butoxy-2-propanol	5131-66-8	UA 7700000	-	225-878-4
2-propylene glycol 1-phenyl ether	2PGlPhE, l-phenoxy-2-propanol	770-35-4	UB 8886500	-	212-222-7
1-propylene glycol 2-methyl ether	1PG2ME, 2-methoxypropanol-l	1589-47-5	UB 7645000	-	216-455-5
1-propylene glycol 2-methyl ether 1-acetate	1PG2MEA, 2-methoxy-l-acetoxypropane	70657-70-4	AI 8967450	-	274-724-2
dipropylene glycol (mono)methyl ether	DPGME	34590-94-8	JM 1575000	-	252-104-2
dipropylene glycol (mono)ethyl ether	DPGEE, 2-ethoxymethoxyethoxypropanol	15764-24-6	JM 1225000	-	-
tripropylene glycol (mono)methyl ether	TPGME	25498-49-1	UB 8070000	-	247-045-4

Table 11.2 Physical and chemical properties of the glycol ethers and their esters (ECETOC, 1995)

Glycol ether

Molecular formula

Structural formula

(°c)

Boiling point (°C at 1013 hPa)

Vapour pressure (hPa @ 20 °C (25 °C))

egme

c3h8o2

ch3"^ ch2 oh

76.09

-85.1

124

6.2 (9.7)

egmea

118.1

-65

145

9.3

maa

C3h603

ch3 ch3 ^oh

90.09

approx. 7

202

1.8

egee

C4H10°2

ch2 ch2 ^oh ch3^ ^o ch2

90.1

<-80

135-137

egeea

C6H12°3

c ch2^ 0^ ch3 ch3^ o ch2 ch2

132.2

-62

153-159

egnpe

C5H12°2

ch2^ 0^ ch2^ ch3 ch2 ch2 oh

104.2

approx. -60

150-152

Table 11.2 Physical and chemical properties of the glycol ethers and their esters (ECETOC, 1995) continued

Glycol ether

Molecular formula

Structural formula

(°c)

Boiling point (°C at 1013 hPa)

Vapour pressure (hPa @ 20 °C (25 °C))

EGnPEA

0-ch2

ch2 ch3

146.2

173

0.67

EGiPE

C5H12°2

ch, ^ch3

104.2

< -60

144

(6.9)

EGBE

c6h14o2

ch2^ ch2 ch2^ .oh

118.2

-77

171

(1.17)

EGBEA

C8H16°3

c ch2^ ch2^ ch3 ch3 0 ch2 ch2 ch2

160.2

-64

192

Table 11.2 Physical and chemical properties of the glycol ethers and their esters (ECETOC, 1995) continued

Glycol ether

Molecular formula

Structural formula

(°c)

Boiling point (°C at 1013 hPa)

Vapour pressure (hPa @ 20 °C (25 °C))

egphe

r^i °H

138.2

246

0.04

egdme

C4H10°2

o^ ch2 ch3 ch3^ ch2

90.1

-58 to -71

egdee

c6h14o2

ch2 ch2^ /o /ch3 ch3 ^o ch2 ^ch2

118.2

-74

121

12.5 (16.5)

degme

o ch2 ch2 oh

120.1

-85

190-196

(0.24)

degee

C6H14°3

ch2 ch2^ o^ /ch2 ch3^ o ch2 ch2 ^oh

134.2

-76

197-205

Table 11.2 Physical and chemical properties of the glycol ethers and their esters (ECETOC, 1995) continued
Glycol ether	Molecular formula	Structural formula	Molecular mass	Melting point (°C)	Boiling point (°C at 1013 hPa)	Vapour pressure (hPa @ 20 °C (25 °C))
degeea	C8H15°4	ch2 ch2^ /ch2 i chjT o ch2 ch2 ^o ch3	176.2	-25	210-220	0.13
degbe	ch3^ ch2 ch2 ch2 oh	162.2	-68	230	(0.057)
degbea	C10H20O4	i ch2^ 0^ ch2 ch2^ ch2 ch3 0 ch2 ch2 ^0 ch2 ^ch3	204.3	nk	247	<0.013
degdme	ch3^ ch2 ^0 ch2 ch3	134.2	-68	162	2.27
degdee	ch3^ ^ ^ch2 cnf ^ ^ch3	162.2	nk	189	(0.67)
tegme	c7h16o4	ch2^ 0^ ch2 ch2^ 0 ho ch2 ch2 ^0 ch2 ^ch3	164.2	-44	249.2	<0.013

Table 11.2 Physical and chemical properties of the glycol ethers and their esters (ECETOC, 1995) continued
Glycol ether	Molecular formula	Structural formula	Molecular mass	Melting point (°C)	Boiling point (°C at 1013 hPa)	Vapour pressure (hPa @ 20 °C (25 °C))
tegee	C8H18°4	ch2^ ch2 ch2^ ch3 ho ch2 ch2 o ch2 ch2	178.2	-30	235-280	<0.01
tegbe	c10H22o4	ho^ ch2 ch2 .cl ch2 ch2 ch2 \ / \ / \ / \ / \ / \ / \ ch2 ^o ch2 ch2 ^o ch2 ch3	206.3	-35	255-295	<0.01
tegdme	C8H1804	ch3 ch2 ^o ch2 ch2 ^o	178.2	-40	210-230	1.2
2pg1me	CH3 CH2 CH3	90.1	-96	120	12
2pg1mea	ch3 ch2 ^ch3	132.2	< -67	145.8	4.9

Table 11.2 Physical and chemical properties of the glycol ethers and their esters (ECETOC, 1995) continued

Glycol ether

Molecular formula

Structural formula

Molecular mass

Melting point (°C)

Boiling point (°C at 1013 hPa)

Vapour pressure (hPa @ 20 °C (25 °C))

2pg1ee

ch2 ch2 ch3

104.2

-90

132

2pg1eea

ch3 0 ch ^c ch3 0

146.2

-89

158

2.026

2pg1be

ch2 ch2 ch2 oh

132.2

< -75

170.2

0.8

2PGlPhE

C9H12°2

^ ch ^ch3

152.2

approx. 13

242.7

(0.05)

1PG2ME

ch^ oh ch3 ch2

90.1

< -50

130-133

Table 11.2 Physical and chemical properties of the glycol ethers and their esters (ECETOC, 1995) continued
Glycol ether	Molecular formula	Structural formula	Molecular mass	Melting point (°C)	Boiling point (°C at 1013 hPa)	Vapour pressure (hPa @ 20 °C (25 °C))
		0
1PG2MEA	0	132.2	approx. <20	150-151	2.9
		ch3
DPGME	ch2 ch ^oh ch3	148.2	-83	184-197	1
		ch3
DPGEE	ch;t ch2 ch ^oh ch3	162.2	< -50	188.3	56.67
		ch3
TPGME	c10h22o4	0 ch2 ch^ ch2 ch3x ch^ ch2 ch^ ^oh ch3 ch3	206.3	-78	242.2

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